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微量Cu元素对Au-24Ag-3.25Si钎料合金组织和焊接性能的影响
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Effect of Minor Cu on Microstructure and Welding Performance of Au-24Ag-3.25Si Brazing Alloy
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    摘要:

    通过分析相图,配制成分分别为Au-24Ag-3.25Si、Au-24Ag-3.25Si-1.5Cu、Au-24Ag-3.25Si-2.0Cu、Au-24Ag-3.25Si-2.5Cu4种合金,中频感应真空熔铸法制备铸锭,在流动氢气保护管式电阻炉中进行焊接实验,基板采用纯Ni片,焊接温度为550 ℃。使用微量型DTA差热分析仪测定钎料合金的熔化温度,并通过金相观察和扫描电镜观察结合X射线能谱分析对钎料合金的组织和焊接性能进行研究。结果表明,添加适量的Cu元素能降低Au-24Ag-3.25Si钎料合金的熔点,

    Abstract:

    By analyzing the phase diagram, four kinds of alloys with different component, Au-24Ag-3.25Si, Au-24Ag-3.25Si-1.5Cu, Au-24Ag-3.25Si-2.0Cu, Au-24Ag-3.25Si-2.5Cu(wt%) were prepared by the vacuum melting method in a medium-frequency induction furnace. The welding experiment was done in a tube type resistance furnace with flow H2 as protective gas, the welding temperature was 550 ℃ and the base plate is pure Ni sheet. The melting temperature was measured by a microscale DTA analyzer and the microstructure and welding performance of the brazing alloy were studied by metallographic and SEM analysis together with X-ray energy spectrum analysis. The results show that the addition of proper Cu can reduce the melting temperature and the interval between solidus and liquidus of the Au-24Ag-3.25Si brazing alloy. The microstructure of the alloy was also changed greatly because of the addition of Cu. There is a new type of solid solution formed, which makes the microhardness of the alloy increased accordingly. The spreading pattern is fine and the wetting angle is small after the Au-24Ag-3.25Si-1.5Cu brazing alloy welding with Ni, whose welding interface structure is almost the same as that without Cu. There is also IMC layer in the interface and the X-ray energy spectrum analysis show that the IMC layer is Ni-Si intermetallic. The addition of Cu will not improve the welding performance of the Au-24Ag-3.25Si brazing alloy with Ni obviously

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崔大田,王志法,姜国圣.微量Cu元素对Au-24Ag-3.25Si钎料合金组织和焊接性能的影响[J].稀有金属材料与工程,2009,38(3):439~442.[Cui Datian, Wang Zhifa, Jiang Guosheng. Effect of Minor Cu on Microstructure and Welding Performance of Au-24Ag-3.25Si Brazing Alloy[J]. Rare Metal Materials and Engineering,2009,38(3):439~442.]
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  • 收稿日期:2008-02-21
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