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Mg-Zn-Si体系的相平衡计算及应用
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国家科技支撑计划(2007BAE09B03);贵州省“十一五”重大专项(20066003);中国铝业公司科技发展基金(2007KJA07)


Thermodynamic Calculation of Phase Equilibria in the Mg-Zn-Si System and Its Application
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    摘要:

    利用Calphad方法重新评估了Mg-Si二元系的液相,并结合Mg-Zn和Zn-Si二元系热力学数据,外推得到Mg-Zn-Si三元系热力学参数;同时根据Mg2Si-MgZn2伪二元相图实验数据评估了Mg-Zn-Si系的液相三元相交互作用参数,计算相图与实验数据较一致。利用Scheil凝固模型模拟了Mg-2.33Zn-0.9Si(at%)合金的凝固过程,预测了镁合金在铸造冷却过程中的相演变信息,模拟计算结果与实验结果吻合较好

    Abstract:

    The liquid phase of the Mg-Si binary system was re-assessed by the Calphad approach. Combined the thermodynamic data of Mg-Zn and Zn-Si binary systems, the thermodynamic parameters of Mg-Zn-Si ternary system were obtained by extrapolation. Based on the phase diagram of Mg2Si-MgZn2 pseudo-binary system, the liquid ternary interaction parameters of Mg-Zn-Si system were assessed. The results show that the calculated phase diagram agrees basically with the experimental data. The solidification process of the Mg-2.33Zn-0.9Si (at%) alloy was simulated by Scheil model, and the phase evolution of Mg alloy during cooling casting was predicted. The results agree with the previous experiment results

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赵阳子,赵云鹤,李 谦,陈双林,张捷宇,周国治. Mg-Zn-Si体系的相平衡计算及应用[J].稀有金属材料与工程,2010,39(8):1385~1389.[Zhao Yangzi, Zhao Yunhe, Li Qian, Chen Shuanglin, Zhang Jieyu, Zhou Guozhi. Thermodynamic Calculation of Phase Equilibria in the Mg-Zn-Si System and Its Application[J]. Rare Metal Materials and Engineering,2010,39(8):1385~1389.]
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  • 收稿日期:2009-08-27