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报废银钨触头回收银和钨的工艺研究
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国家科技支撑计划项目(2008BAC46B04);江苏省高校科研成果产业化推进项目(JH09-16);江苏技术师范学院基础及应用基础研究基金项目(KYY08018)


Recycling Process of Silver and Tungsten from Waste Ag-W Alloy Contact
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    摘要:

    银钨合金触点是重要的电接触材料,报废银钨触点中银钨的分离和资源化问题引起了越来越多的重视。以报废银钨触头为原料,提出了“一次分银-焙烧-二次分银”的回收工艺,考察了银钨分离的工艺条件,通过实践验证了其可靠性,银、钨的回收率达到99%以上。回收得到的银和钨可分别深加工成粒度为0.3~0.6 μm的超细银粉和纯净的WO3产品。

    Abstract:

    Ag-W alloy contact is one kind of important electrical contact materials, and the separation and recycling of sliver and tungsten from waste Ag-W alloy contact has attracted more and more attention for the resource value and secondary pollution during the recycling process. A novel process about the separation and recycling of sliver and tungsten from waste Ag-W alloy contact has been proposed, which includes 4 steps of first leaching silver, roasting, secondary leaching silver and ammonia leaching. The result shows that the recovery rate of Ag and W is higher than 99%, and 0.3-0.6 μm superfine silver powders and pure WO3 powders can be obtained during the recycling process.

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王 琪,娄德大,徐元萍,周全法.报废银钨触头回收银和钨的工艺研究[J].稀有金属材料与工程,2011,40(10):1817~1821.[Wang Qi, Lou Deda, Xu Yuanping, Zhou Quanfa. Recycling Process of Silver and Tungsten from Waste Ag-W Alloy Contact[J]. Rare Metal Materials and Engineering,2011,40(10):1817~1821.]
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  • 收稿日期:2010-10-20
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