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镁合金与不锈钢的瞬间液相扩散连接
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西安科技大学

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TG457

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Transient Liquid Phase Bonding of Magnesium Alloy AZ31B and 304 Stainless Steel
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Xi’an University of Science and Technology

Fund Project:

National Natural Science Foundation of China (50901062, 51271152)

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    摘要:

    以Cu为中间夹层对AZ31B镁合金与304不锈钢进行瞬间液相扩散连接,研究了焊接接头的微观结构和连接强度。结果表明,510℃×30min、530℃×10min时,接头界面区没有出现共晶液相,界面结合较弱;520℃×30min、530℃×20min时,接头界面区形成Mg-Cu共晶液相,焊缝宽度显著增加,界面结合强度提高;530℃×30min,镁基体向共晶液相溶解,镁基体一侧形成350μm的层状扩散区,接头界面依靠共晶液相在不锈钢基体表面的润湿铺展形成冶金结合,接头显微组织依次是Mg-Cu共晶组织层、富Mg固溶体层、弥散分布于镁合金基体的Mg17(Cu,Al)12相和分布于镁合金晶界的Mg-Cu-Al三元化合物所组成的镁合金基体渗透区,其剪切强度达到最大(52MPa);540℃×30min、530℃×40min时,界面扩散区的共晶液相发生等温凝固,镁合金基体晶界处Mg-Cu-Al三元金属间化合物呈连续网状分布,接头的剪切强度降低。AZ31B基体发生了再结晶及晶粒长大,530℃×30min产生退火孪晶,540℃×30min时晶粒内析出第二相并显著长大,基体出现了不同程度的软化现象

    Abstract:

    Transient liquid-phase bonding of magnesium alloy (AZ31B) to stainless steel (304) was performed using a copper interlayer. The microstructure and bonding strength of the bonded joint were studied. The results show that when the welding condition is 510℃×30min or 530℃×10min, no eutectic phase was observed in the welded joint and the metallurgical bond is weak. When the welding condition is 520℃×30min or 530℃×20min, the joint interface produces Mg-Cu eutectic. A significant increasing occurs in weld width and interfacial bonding strength increases too. At 530℃×30min, the magnesium matrix dissolves into the eutectic liquid , and the laminar diffusion region with a width of about 350μm forms in the welded joint at the magnesium side, besides,the interface forms a metallurgical bond relying on the Mg-Cu eutectic liquid wetting and spreading to the stainless steel surface. Microstructure followed by Mg-Cu eutectic layer, Mg-rich solid solution layer , Mg17(Cu,Al)12 dispersed in magnesium alloy matrix and permeability zones of Mg-Cu-Al ternary compounds distributed in grain boundaries of magnesium alloy. The shear strength of the joint reaches the highest value of (52MPa). With the welding condition of 540℃×30min or 530℃×40min, eutectic liquid on interfacial diffusion zone occurs isothermal solidification and the joint shear strength decreases, which attributed to continuous network distributed of Mg-Cu-Al compound along the magnesium grain boundary. Recrystallization and grain growth happens to AZ31B matrix, and twins produced at 530℃×30min. The second phase precipitates within the grains and significantly grows at 540℃×30min. AZ31B matrix appears different degrees of softening phenomenon.

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引用本文

杜双明.镁合金与不锈钢的瞬间液相扩散连接[J].稀有金属材料与工程,2016,45(8):2064~2070.[Du Shuangming. Transient Liquid Phase Bonding of Magnesium Alloy AZ31B and 304 Stainless Steel[J]. Rare Metal Materials and Engineering,2016,45(8):2064~2070.]
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历史
  • 收稿日期:2014-07-09
  • 最后修改日期:2014-11-15
  • 录用日期:2015-02-06
  • 在线发布日期: 2016-10-09
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