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Mn/B复合添加对铝硅合金富铁相特征的影响
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广州有色金属研究院 金属加工与成型技术研究所,广州有色金属研究院 金属加工与成型技术研究所,广州有色金属研究院 金属加工与成型技术研究所,广州有色金属研究院 金属加工与成型技术研究所,广州有色金属研究院 金属加工与成型技术研究所

基金项目:

广东省金属强韧化技术与应用重点实验室建设项目(2014B030301012);广东省金属材料与加工专业镇联合创新公共平台建设项目(2013B091602002),广州市先进金属结构材料重点实验室建设项目(201509010003)。


Effect of compound addition Mn/B on the characteristics of iron-rich phase in Al-Si alloy
Author:
Affiliation:

Institute of Metal Processing and Forming Technology,Guangzhou Research Institute of Non-ferrous Metals,Institute of Metal Processing and Forming Technology,Guangzhou Research Institute of Non-ferrous Metals,Institute of Metal Processing and Forming Technology,Guangzhou Research Institute of Non-ferrous Metals,Institute of Metal Processing and Forming Technology,Guangzhou Research Institute of Non-ferrous Metals,Institute of Metal Processing and Forming Technology,Guangzhou Research Institute of Non-ferrous Metals

Fund Project:

International Science Technology Cooperation Program of China (2015DFR50350); Specialized Research Fund for the Doctoral Program of Higher Education (20116118120017); Scientific Research Program Funded by Shaanxi Provincial Education Department (2014JK1531); Innovation Project of Xi'an Institute of Technology (2014CX024)

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    摘要:

    在含1.0?的铝硅合金中复合加入一定量的Mn和不同量的B,采用OM、SEM、EDS及DSC等手段研究了B含量对铸态组织、富铁相比例及形貌的影响,并探讨了复合添加Mn/B的影响机制。结果表明:适量的B对Al-Si合金晶粒度、富铁相都具有明显的细化作用;添加3%Al-3B时,富铁相面积分数和平均颗粒尺寸分别从6.73%和11.2μm降至4.13%和7.5μm;在3%之内添加Al-3B可抑制粗大初生铁相的形成,促进富铁相由粗大星状初生铁相、大尺寸树枝状、网状共生富铁相向小尺寸致密度高的树枝状、汉字状和粒状富铁相状变;过量的Al-3B易导致多边形初生铁相的出现,但合金组织和共生铁相得到进一步的细化。

    Abstract:

    The effect of B addition on the morphology of iron-rich phase in Al-Si alloy with ?1.0% Fe and ?1.0% Mn was invesitigated with optical microscopy, SEM, EDS and DSC. The obtained results show that an appropriate amount of B addition results in not only an obvious refinement on Al-Si alloy grain, but also the morphology, size and volume fraction of the iron-rich phases. With 3% Al-3B addition, the volume fraction and mean size of the iron-rich phases were reduced to 4.13% and 7.5 μm, respectively. With the increase of Al-3B addition within 3%, the formation of coarse primary iron-rich phase has been suppressed, and the primary coarse iron phase, large size dendritic iron-rich phase and netlike iron-rich phase are transformed into small size and high density of dendritic, chinese script shaped and granular. However, excessive Al-3B addition leads to the formation of polygon primary iron rich phase and refined grain size and iron-rich phase.

    参考文献
    [1] Dinnis Cameron M, Taylor Jone A, Dahle Arne K. As-cast morphology of iron-intermetallics in Al–Si foundry alloys[J]. Scripta Materialia,2005,53(8):955–958.
    [2] Taylor Jone A. Iron-containing intermetallic phases in Al-Si based casting alloys[J] .Procedia Materials Science 1.2012:19 – 33
    [3] Yin Fei(印飞), Yang Jiang-bo(杨江波),Sun Bao-de(孙宝德). Solidificat ion Behaviors and Microstructure Morphology of Iron Phase in Al-Si Alloys with Higher Iron Content[J]. JOURNAL OF SHANGHAI JIAOTONG UNIVERSITY(上海交通大学学报), 2002, 01:43-46 50.
    [4] Shabestari S G.The effect of iron and manganese on the formation of intermetallic compounds in aluminum–silicon alloys[J]. Materials Science and Engineering A, 2004, 383: 289–298.
    [5] Gustafsson G, Thorvaldsson T , Dunlop G L. The influence of Fe and Cr on the microstructure of cast Al-Si Mg alloy[J]. Metallurgical Transact ions A. 1986, 17A ( 1) : 45~ 52.
    [6] Murali S, Raman KS, Murthy K S S. The formation of β-FeSiA15 and Be-Fe phases in A1-7Si-0.3Mg alloy containing Be[J]. Materials Science and Engineering A, 1995 190:165-172.
    [7] Samuel A M, Samuel F H, Dotty H W. Observation on the formation of β-Al5FeSi phase in 319 type Al–Si alloys[J]. J. Materials Science, 1996.31: 5529–5539.
    [8] Tan Xi-ping(谭喜平), Zheng Kai-hong(郑开宏), Song Dong-fu(宋东福),et al. Effects of A1-3B master alloy addition on impurity iron content of recycled casting aluminum alloy[J]. The Chinese Journal of Nonferrous Metals(中国有色金属学报), 2014,06:1401-1407.
    [9] Fan Chao(范超), Long Siyuan(龙思远), Wu Mingfang(吴明放),et al.Effect of Ce-Rich Mischmetal Addition on Microstructure and Tensile Properties of Secondary Al-Si Alloys[J]. Rare Metal Materials and Engineering(稀有金属材料与工程), 2014, 43(12):3073-3077.
    [10] Tzeng Yu-Chih, Wub Chih-Ting, BOR Hui-Yun, et al. Effects of scandium addition on iron-bearing phases and tensile propertiesofAl–7Si–0.6Mg alloys[J]. Materials Science Engineering A, 2014,593;103–110.
    [11] Liu Xiang-fa(刘相法),Bian Xiu-fang(边秀房),LiuYu-xian(刘玉先), et al.The Heredity of Iron Compound Morphologies in Al Alloys and Spheroidizing Mechanism[J]. ACTA METALLURGICA SIN ICA(金属学报), 1997,10:1062-1067.
    [12] Zhang Lei(张磊), Jiao Wan-li(焦万丽), YU Hai-jun(尉海军),et al. Influence of manganese and pre-heat treatment on microstructure and mechanical properties of Al- Si alloy[J]. The Chinese Journal of Nonferrous Metals(中国有色金属学报), 2005,03:368-373.
    [13] Salem Seifeddine, Sten Johansson, Ingvar L. The influence of cooling rate and manganese content on the β-Al5FeSi phase formation and mechanical properties of Al–Si-based alloys[J]. Materials Science and Engineering A,2008,490 :385–390.
    [14] Tan Xi-ping(谭喜平),Song Dong-fu(宋东福),Zheng Kai-hong(郑开宏),et al. Microstructure and Mechanical Properties of Aluminum Alloy Recycled by Cast with Mechanical Vibration[J]. CHINESE JOURNAL OF RARE METALS(稀有金属), 2014,02: 185-192. Tan Xi-ping(谭喜平),Song Dong-fu(宋东福),Zheng Kai-hong(郑开宏),et al.Microstructure and Mechanical Properties of Aluminum Alloy Recycled by Cast with Mechanical Vibration[J]. CHINESE JOURNAL OF RARE METALS(稀有金属), 2014,02: 185-192.
    [15] Ji Shou-xun, Yang Wen-chao, Gao Feng, et al. Effect of iron on the microstructure and mechanical property of Al?Mg?Si?Mn and Al?Mg?Si diecast alloys[J].Materials Science and Engineering A, 2013, 564: 130?139.
    [16] Ceschini L, Boromei I, Morria A, et al. Effect of Fe content and microstructural features on the tensile and fatigue properties of the Al?Si10?Cu2 alloy[J]. Materials and Design, 2012, 36: 522?528.
    [17] Song Dong-fu(宋东福), Wang Shun-cheng(王顺成), Zheng Kai-hong(郑开宏).Effects of Mn/Fe mole ratio on iron-rich phase morphology ofA356 cast aluminum alloy[J]. The Chinese Journal of Nonferrous Metals(中国有色金属学报), 2015,25(7): 1832-1838.
    [18] Yang Huai-de(杨怀德), Long Si-yuan, Wu Ming-fang, et al. Mechanism of Iron Removal from Secondary Al-Si Melt by Boron Compounds and Mn[J]. Rare Metal Materials and Engineering(稀有金属材料与工程),2015,44(3):621-627.
    [19]Fan Chao(范超), Long Si-yuan(龙思远), Yang Huai-de(杨怀德, et al. Effect of Mn and Ce on the Fe-Rich Intermetallics in Secondary Al-Si Alloys[J]. Rare Metal Materials and Engineering(稀有金属材料与工程), 2014,43(3):660-664.
    [20] Hillis J E,Green W G..Method for removing iron contamination from magnesium. USA. 4773930, 1988.
    [21] Gao J W, Shu D, Wang J. Sun B D. Effects of Na2B4O7 on the elimination of iron from aluminum melt[J]. Scripta Materialia, 2007,57:197-200.
    [22] Cao X, Campbell J. The Solidification Characteristics of Fe-Rich Intermetallics in A1-11.5Si-0.4Mg Cast Alloys[J]. Metallurgical Materials Transactions A, 2004, 35(5):1425-1435.
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引用本文

宋东福,周楠,徐静,王顺成,郑开宏. Mn/B复合添加对铝硅合金富铁相特征的影响[J].稀有金属材料与工程,2016,45(8):2133~2138.[SONG Dong-fu, ZHOU Nan, XU Jing, WANG Shun-cheng, ZHENG Kai-hong. Effect of compound addition Mn/B on the characteristics of iron-rich phase in Al-Si alloy[J]. Rare Metal Materials and Engineering,2016,45(8):2133~2138.]
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  • 收稿日期:2015-11-03
  • 最后修改日期:2016-01-18
  • 录用日期:2016-03-30
  • 在线发布日期: 2016-10-09