含复合(Ti,Mo)C析出相的马氏体钢的氢捕获与解吸附

Hydrogen trapping and desorption in a martensitic steel with mixed (Ti,Mo)C precipitates

摘要:

采用热脱氢分析装置 (TDS) 研究了含复合 (Ti,Mo)C析出相的马氏体钢的氢的捕获与解吸附行为。结果表明,36-60 nm的未溶球形(Ti,Mo)复合析出相在室温电化学充氢过程中不能捕获氢,而回火析出的1-5 nm的复合 (Ti,Mo)C析出相是有效的氢陷阱,尽管其氢陷阱激活能相对较低,为16.4-22.1 kJ/mol,与晶界、位错处的氢陷阱激活能相近,同时远低于纯的共格TiC析出相的氢陷阱激活能,但在大气中放置时,被回火析出的1-5 nm的复合 (Ti,Mo)C析出相捕获的氢无法解吸。

Abstract:

Hydrogen trapping and desorption in a martensitic steel with mixed (Ti,Mo)C precipitates have been investigated by means of Thermal Desorption Spectrometry (TDS) analysis. Results indicated that the spherical (Ti,Mo)C precipitates of 36-60 nm could not absorb hydrogen during electrochemical charging, while the (Ti,Mo)C precipitates of 1-5 nm were effective hydrogen trapping sites. In spite of a relatively low desorption activation energy of 16.4 kJ/mol, which is far lower than that from pure coherent TiC, the hydrogen trapped by the fine (Ti,Mo)C carbides could not desorb during atmospheric exposure.