等离子渗镀<bold>CrON</bold>复合涂层结构与抗铝液熔蚀性能

doi:10.12442/j.issn.1002-185X.20200302

首页 > 过刊浏览>2021年第50卷第5期 >1523-1530. DOI:10.12442/j.issn.1002-185X.20200302

等离子渗镀CrON复合涂层结构与抗铝液熔蚀性能
DOI:
                        10.12442/j.issn.1002-185X.20200302
                    
作者:
                        Ahmad Farooq1,2,3Ahmad Farooq
先进金属材料绿色制备与表面技术教育部重点实验室(安徽工业大学)，安徽 马鞍山 243002;安徽工业大学 现代表界面工程研究中心，安徽 马鞍山 243002;安徽工业大学 材料科学与工程学院，安徽 马鞍山 243002
在期刊界中查找
在百度中查找
在本站中查找
张林1,2张林
先进金属材料绿色制备与表面技术教育部重点实验室(安徽工业大学)，安徽 马鞍山 243002;安徽工业大学 现代表界面工程研究中心，安徽 马鞍山 243002
在期刊界中查找
在百度中查找
在本站中查找
郑军1,2,3郑军
先进金属材料绿色制备与表面技术教育部重点实验室(安徽工业大学)，安徽 马鞍山 243002;安徽工业大学 现代表界面工程研究中心，安徽 马鞍山 243002;安徽工业大学 材料科学与工程学院，安徽 马鞍山 243002
在期刊界中查找
在百度中查找
在本站中查找
Sidra Iram1,2,3Sidra Iram
先进金属材料绿色制备与表面技术教育部重点实验室(安徽工业大学)，安徽 马鞍山 243002;安徽工业大学 现代表界面工程研究中心，安徽 马鞍山 243002;安徽工业大学 材料科学与工程学院，安徽 马鞍山 243002
在期刊界中查找
在百度中查找
在本站中查找
张世宏1,2,3张世宏
先进金属材料绿色制备与表面技术教育部重点实验室(安徽工业大学)，安徽 马鞍山 243002;安徽工业大学 现代表界面工程研究中心，安徽 马鞍山 243002;安徽工业大学 材料科学与工程学院，安徽 马鞍山 243002
在期刊界中查找
在百度中查找
在本站中查找

                    
作者单位:1.先进金属材料绿色制备与表面技术教育部重点实验室(安徽工业大学)，安徽 马鞍山 243002;2.安徽工业大学 现代表界面工程研究中心，安徽 马鞍山 243002;3.安徽工业大学 材料科学与工程学院，安徽 马鞍山 243002
作者简介:
通讯作者:
中图分类号:
基金项目:

Microstructure and Corrosion Behavior of Duplex CrON Coatings in Molten Aluminum

Author:

Farooq Ahmad ^{^1,2,3}
Farooq Ahmad
Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials (Anhui University of Technology), Ministry of Education, Maanshan 243002, China;Research Center of Modern Surface & Interface Engineering, Anhui University of Technology, Maanshan 243002, China;School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, China
在期刊界中查找
在百度中查找
在本站中查找
Zhang Lin ^{^1,2}
Zhang Lin
Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials (Anhui University of Technology), Ministry of Education, Maanshan 243002, China;Research Center of Modern Surface & Interface Engineering, Anhui University of Technology, Maanshan 243002, China
在期刊界中查找
在百度中查找
在本站中查找
Zheng Jun ^{^1,2,3}
Zheng Jun
Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials (Anhui University of Technology), Ministry of Education, Maanshan 243002, China;Research Center of Modern Surface & Interface Engineering, Anhui University of Technology, Maanshan 243002, China;School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, China
在期刊界中查找
在百度中查找
在本站中查找
Iram Sidra ^{^1,2,3}
Iram Sidra
Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials (Anhui University of Technology), Ministry of Education, Maanshan 243002, China;Research Center of Modern Surface & Interface Engineering, Anhui University of Technology, Maanshan 243002, China;School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, China
在期刊界中查找
在百度中查找
在本站中查找
Zhang Shihong ^{^1,2,3}
Zhang Shihong
Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials (Anhui University of Technology), Ministry of Education, Maanshan 243002, China;Research Center of Modern Surface & Interface Engineering, Anhui University of Technology, Maanshan 243002, China;School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, China
在期刊界中查找
在百度中查找
在本站中查找

Affiliation:

1.Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials (Anhui University of Technology), Ministry of Education, Maanshan 243002, China;2.Research Center of Modern Surface & Interface Engineering, Anhui University of Technology, Maanshan 243002, China;3.School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, China

Fund Project:

Anhui Provincial Natural Science Foundation (2008085QE202); Anhui Provincial Key Research and Development Program (202004h07020020, 202004b11020011); Xijiang Innovation Team Project Funding of Zhaoqing

摘要

图/表

访问统计

参考文献 [35]

相似文献 [20]

引证文献

资源附件

文章评论

摘要:

采用等离子渗氮/电弧离子镀复合方法在H13模具钢表面制备出CrON涂层，研究氧流量对CrON复合涂层结构及抗铝液熔蚀性能的影响。结果表明，随着氧流量的增加，所制备的涂层主要物相由氮化物向氧化物转变，在氧流量较低时主要呈现面心立方CrN结构，而在氧流量为200 mL/min时制备的涂层形成典型的Cr₂O₃晶体相特征。掺入适量的氧，CrN涂层柱状晶生长受到抑制，涂层结构更加致密。涂层表面缺陷和粗糙度随着氧含量的增加而增大。CrON复合涂层在铝液中的失效形式是局部点蚀。由于形成致密的结构和良好的热稳定性，在氧流量为50 mL/min时制备的涂层具有优异的抗铝液熔蚀能力，而氧流量较高时表面生成致密的Cr₂O₃抗氧化层也有利于提高抗铝液熔蚀性能。

关键词:CrON;复合涂层;微观结构;热熔蚀;铝液

Abstract:

The duplex CrON coatings were prepared on H13 tool steels by combination of plasma nitriding and arc ion plating. The effects of oxygen flow rate on microstructure and corrosion behavior of duplex CrON coating in the molten aluminum were investigated. Results show that the as-deposited coatings with oxygen flow rate of 0, 50, and 100 mL/min, namely CrON-0, CrON-50, and CrON-100 coatings, mainly consist of B1-CrN phase. The major components of CrON coating change from nitride into oxide phase with increasing the oxygen flow rate, and the Cr₂O₃ crystalline phase is obviously observed in the as-deposited coatings with oxygen flow rate of 200 mL/min, namely CrON-200 coating. Oxygen addition in nitride restrains the columnar growth of grains resulting in the dense microstructure. The surface defects and roughness increase with the increase of oxygen content. The failure behavior of duplex CrON coatings is mainly corrosion pitting in molten aluminium. The CrON-50 coating reveals the best corrosion resistance due to the dense columnar microstructure and high thermal stability. The dense Cr₂O₃ layer in CrON-200 coating is also favourable for corrosion protection against the molten aluminum.

Key words:CrON;duplex coating;microstructure;immersion corrosion;molten aluminum

参考文献

[1] Jhavar S, Paul C P, Jain N K. Engineering Failure Analysis[J], 2013, 34: 519

[2] Chang S H, Lin Y K, Huang K T. Surface and Coatings Technology[J], 2012, 207: 571

[3] Sokovic M, Panjan P, Kim R. Journal of Materials Processing Technology[J], 2004, 157-158: 613

[4] Das K, Alphonsa J, Ghosh M et al. Surfaces and Interfaces[J], 2017, 8: 206

[5] Peng J H, Zhu Z Z, Su D Y. Tribology International[J], 2019,129: 232

[6] Navin?ek B, Panjan P, Gorenjak F. Surface and Coatings Technology[J], 2001, 137: 255

[7] Chim Y C, Ding X Z, Zeng X T et al. Thin Solid Films[J], 2009, 517: 4845

[8] Ho W Y, Huang D H, Huang L T et al. Surface and Coatings Technology[J], 2004, 177-178: 172

[9] Ren Xingrun, Huang Zhu, Liu Meixia et al. Rare Metal Materials and Engineering[J], 2018, 47(4): 1100 (in Chinese)

[10] Shao T, Ge F F, Dong Y et al. Wear[J], 2018, 416-417: 44

[11] Hsu C H, Chen Y D. Thin Solid Films[J], 2009, 517: 1655

[12] Castaldi L, Kurapov D, Reiter A et al. Surface and Coatings Technology[J], 2008, 203: 545

[13] Ho W Y, Hsu C H, Huang D H et al. Surface and Coatings Technology[J], 2005, 200: 1303

[14] Warcholinski B, Gilewicz A, Lupicka O et al. Surface and Coatings Technology[J], 2017, 309: 920

[15] Suzuki K, Suematsu H, Thorogood G J et al. Thin Solid Films[J], 2017, 625: 111

[16] Warcholinski B, Gilewicz A, Kuprin A S et al. Vacuum[J], 2018, 156: 97

[17] Kuprin A S, Kuznetsova T A, Gilewicz A et al. Problems of Atomic Science and Technology[J], 2016, 106: 211

[18] Li W Z, Yi D Q, Li Y Q et al. Journal of Alloys and Compounds[J], 2012, 518: 86

[19] Minami T, Nishio S, Murata Y. Surface and Coatings Technology[J], 2014, 254: 402

[20] Dobrzanski L A, Zukowska L W, Kubacki J et al. Archives of Materials Science and Engineering[J], 2008, 32: 99

[21] Yun J S, Hong Y S, Kim K H. Journal of the Korean Physical Society[J], 2010, 57: 103

[22] Ramm J, Neels A, Widrig B et al. Surface and Coatings Technology[J], 2010, 205: 1356

[23] Biesinger M C, Payne B P, Grosvenor A P et al. Applied Surface Science[J], 2011, 257: 2717

[24] Wang X B, Zhang X M, Li Q Y et al. Solar Energy Materials and Solar Cells[J], 2018, 188: 81

[25] Suzuki T, Saito H, Hirai M et al. Thin Solid Films[J], 2002, 407: 118

[26] Urgen M, Ezirmik V, Senel E et al. Surface and Coatings Technology[J], 2009, 203: 2272

[27] Chen H Y, Lu F H. Thin Solid Films[J], 2006, 515: 2179

[28] Barshilia H C, Rajam K S. Journal of Materials Research[J], 2004, 19: 3196

[29] Fleischer K, Caffrey D, Farrell L et al. Thin Solid Films[J], 2015, 594: 245

[30] Ho W Y, Shen C H, Chang C L et al. Surface and Coatings Technology[J], 2007, 202: 745

[31] Chang S H, Huang K T, Wang Y H. Materials Transactions[J], 2012, 53: 745

[32] Dinu M, Mouele E S M, Parau A C et al. Coatings[J], 2018, 8: 17

[33] Molinari A, Pellizzari M, Straffelini G et al. Surface and Coatings Technology[J], 2000, 126: 31

[34] Joshi V, Srivastava A, Shivpuri R. Wear[J], 2004, 256: 1232

[35] Nazari K A, Shabestari S G. Journal of Alloys and Compounds[J], 2009, 478: 523

引用本文

Ahmad Farooq,张林,郑军,Sidra Iram,张世宏.等离子渗镀CrON复合涂层结构与抗铝液熔蚀性能[J].稀有金属材料与工程,2021,50(5):1523~1530.[Farooq Ahmad, Zhang Lin, Zheng Jun, Iram Sidra, Zhang Shihong. Microstructure and Corrosion Behavior of Duplex CrON Coatings in Molten Aluminum[J]. Rare Metal Materials and Engineering,2021,50(5):1523~1530.]
DOI：10.12442/j. issn.1002-185X.20200302

复制

文章指标

点击次数:659
下载次数: 1145
HTML阅读次数: 323
引用次数: 0

历史

收稿日期:2020-05-09
最后修改日期:2020-07-15
录用日期:2020-07-20
在线发布日期: 2021-07-19
出版日期: 2021-05-25

首页

期刊简介

编委会

投稿指南

过刊浏览

联系我们

English

引用本文

文章指标

历史

首 页

期刊简介

编委会

投稿指南

过刊浏览

联系我们

English

引用本文

文章指标

历史

首页