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活性Al制氢技术的发展及展望
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兰州理工大学 省部共建有色金属先进加工与再利用国家重点实验室

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中图分类号:

480.99;TB34;TK91

基金项目:

国家自然科学基金资助(项目号51675256)


Hdrogen Produced by Activated Aluminum Splitting Water: State of the Arts
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The National Natural Science Foundation of China (51675256)

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    摘要:

    氢能是理想的能源载体,活性金属分解水制氢具有固态含能、现场制氢、按需供氢,且对水质要求低等特点。本文从Al/H2O反应热力学和动力学两方面综述了铝合金活化的共性问题;从影响Al/H2O反应的内因和外因等因素归纳了活性铝工程化的可行途径。采用多元合金化和合适的制备工艺是活化铝的有效途径;活性铝制氢技术工程化应用的潜力与突破是极端环境。此外,指出Al/H2O自发反应的预判性研究、可持续反应的定量性研究、产业化中产物的循环再利用问题等是活性Al制氢技术进一步发展的方向。最终实现成本低廉、环境友好、安全可靠的活性铝分解水制氢技术的工业化应用。

    Abstract:

    Hydrogen energy is an ideal energy carrier. Hydrogen production from activated metal splitting water has the characteristics of solid-state containing energy, in-situ hydrogen production, supplied hydrogen on demand, and lower requirements for water quality. In this paper, the common problems of activated aluminum alloy are reviewed from the thermodynamics and the kinetics of Al/H2O reaction, and the feasible methods of engineering applied are summarized from the internal factors and the external factors affecting Al/H2O reaction. The key issue of activated aluminum is to adopt multi-element alloying and suitable fabrication processing, and the potential and outbreak of the engineering application of Al/H2O reaction is extreme environment. Moreover, it is pointed out that the predictive investigation and the quantitative investigation of Al/H2O spontaneous reaction, the recycling of Al/H2O reaction products in industrialization are the further development direction. Finally, the industrial application of hydrogen produced by activated aluminum splitting water is low-cost, environment-friendly, safe and reliable.

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张建斌,杨耀民,朱程,臧树俊,石玗.活性Al制氢技术的发展及展望[J].稀有金属材料与工程,2021,50(12):4571~4586.[zhang jianbin, YANG Yaomin, ZHU Cheng, ZANG Shujun, Shi yu. Hdrogen Produced by Activated Aluminum Splitting Water: State of the Arts[J]. Rare Metal Materials and Engineering,2021,50(12):4571~4586.]
DOI:10.12442/j. issn.1002-185X.20200983

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历史
  • 收稿日期:2020-12-19
  • 最后修改日期:2021-01-10
  • 录用日期:2021-02-04
  • 在线发布日期: 2022-01-09
  • 出版日期: 2021-12-24