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Study of Chemical Ordering around the Structural Free Volume in Bulk Amorphous Zr41Ti14Cu12.5Ni10Be22.5 Alloys
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    Abstract:

    Element distribution of the bulk amorphous Zr41Ti14Cu12.5Ni10Be22.5 alloy and of the zone around the structural free volume in the undercooled liquid region was investigated by X-ray diffraction (XRD) and positron annihilation techniques(PAT)-Doppler broadening spectrum. Results show that the structural free volumes in the initially prepared Zr41Ti14Cu12.5Ni10Be22.5 alloy were mainly surrounded by Zr atoms. After the alloy was annealed at 400 ℃ in the undercooled liquid region, both atoms Ti and Be together with Zr were detected to surround the structural free volumes.

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[Zhang Keqin. Study of Chemical Ordering around the Structural Free Volume in Bulk Amorphous Zr41Ti14Cu12.5Ni10Be22.5 Alloys[J]. Rare Metal Materials and Engineering,2009,38(8):1429~1431.]
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History
  • Received:December 14,2008
  • Revised:June 05,2009