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Preparation of Gold Nanochains in 1-Butyl-3-Methylimidazolium Tetrafluoroborate Ionic Liquids
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    Abstract:

    1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid ([BMIM]+[BF4]-) was synthesized using N-methylimidazole and 1-bromobutane as starting materials by two-step method. The obtained ionic liquid was characterized by IR spectra. Gold nanochains were prepared through the reduction of HAuCl4 by NaBH4 in [BMIM]+[BF4]-. UV-Vis spectra and TEM images reveal that the prepared nano gold is mainly chain-like. The ionic liquid not only acts as reaction medium but also as modifier in the preparation of nano gold.

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[Li Zhongchun, Gu Aijun, Zhou Quanfa. Preparation of Gold Nanochains in 1-Butyl-3-Methylimidazolium Tetrafluoroborate Ionic Liquids[J]. Rare Metal Materials and Engineering,2009,38(8):1454~1457.]
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  • Received:July 25,2008