+Advanced Search
In situ preparation MgCr-LDH layer on MAO coating of Mg alloy and study its anti-corrosion protection mechanism
Author:
Affiliation:

1.School of Materials Science and Engineering,Fuzhou University,New Campus,Minhou,Fujian Province;2.School of Materials Science and Engineering,Harbin Institute of Technology

  • Article
  • | |
  • Metrics
  • |
  • Reference [30]
  • |
  • Related [20]
  • | | |
  • Comments
    Abstract:

    A high corrosion resistant and active protection composite coating designed combining Layered Double Hydroxides (LDH) layer and Micro-arc Oxidation (MAO) to further improve the anti-corrosion of Mg alloy. In this paper, MgCr-LDHs/MAO composite coating prepared through in-situ growing LDH layer including NO3- on the surface of MAO coating. The morphology、composition and microstructure of MgCr-LDHs/MAO composite coating were characterized by XRD, XPS, FT-IR, SEM, besides the interaction of LDH and original MAO coating was investigated. The corrosion properties of MgCr-LDHs/MAO coating was tested through immersion in 3.5wt%NaCl solution and electrochemical experiments. The results show that: (1) the LDHs forms a dense sheet like layer on the original MAO coating surface, which can effectively cover the inherent defects of MAO coating, and LDH layer is preferentially formed in the pores of original MAO coating. (2) LDHs don"t damage the original MAO coating during the growth process, besides the adhesion of LDH layer and MAO layer are strong and stable. (3) The composite coating showed the most superior corrosion protection, since MgCr-LDH layer growing on the original MAO coating can hinder the penetration of chloride ions and effectively adsorb a large number of NO3? to exchange Cl- in corrosion solution.

    Reference
    [1]Bowen P K, Drelich J, Goldman J. Acta Biomaterials[J], 2014, 10(3):1475~1482
    [2]Wang X J, Xu D K, Wu R Z, et al. Journal Materials Science Technology[J], 2018. 34: 245~255
    [3]Jang Y, Boyce C, Sankar J, et al. Acta Biomaterials[J], 2013, 9(10):8761~8772
    [4]Ding Wenjiang(丁文江), Wu Yujuan(吴玉娟), Peng Liming(彭立明) et al. Materials China (中国材料进展)[J], 2010, 29(8):37~45.
    [5]Zhang Z W. Journal of the Electrochemical Society[J], 2015, 162: 64~72
    [6]Yang L, Zhang M, Li J, et al. Journal of Alloys Compounds[J], 2009, 471: 197~200.
    [7]Song D, Jing X, Wang J, et al. Corrosion Science[J], 2011, 53: 3651~3656.
    [8]Li Z, Yuan Y, Jing X. Journal of Alloys Compounds[J], 2017, 706: 419~429.
    [9]Toorani M, Aliofkhazraei M, Golabadi M, et al. Effect of lanthanum nitrate on the microstructure and electrochemical behavior of PEO coatings on AZ31 Mg alloy[J]. Journal of Alloys Compounds[J], 2017, 719: 242~255
    [10]Han Y, Song J, Novel. Journal of the American Ceramic Society [J], 2010 92: 1813~1822
    [11]Narayanan T S, Park I S, Min H L. Progress Materials Science [J], 2014 60: 1~55
    [12]Ge Yanfeng(葛延峰), Jiang Bailing(蒋百灵), Li Yulei(李玉磊), et al. Chinese Journal of Materials Research (中国材料研究学报) [J], 2011, 25: 80~83
    [13]Cui L Y, Zeng R C, Guan S K, et al. Journal of Alloys Compounds[J], 2017, 695: 2464~2472
    [14]Chen J F, Lin W X, Shiyan Liang S Y, et al. Applied Surface Science[J], 2019 463: 535~542
    [15]Yasakaua K A, Kuznetsova A, Kallip S, et al.. Corrosion Science [J], 2018, 143: 299~308
    [16]Shi P, Niu B, Shanshan E, et al. Surface Coating Technology[J], 2015, 262: 26~35
    [17]Zhang Y, Yu P H, Wang J P, et al. Applied Surface Science[J], 2018, 433: 927~936
    [18]Zhang F Z, Sun M, Xu S L, et al.. Chemical Engineering Journal[J], 2008, 141: 362~367
    [19]Williams G R, O''Hare D. Journal of Materials Chemistry [J], 2006, 16: 3065~3078
    [20]Li C M, Wei Y Z, Wang X P, et al. Journal of the Taiwan Institute of Chemical Engineers [J], 2018, 85: 193~200
    [21]Khan A I, O''Hare D. Journal of Materials Chemistry [J], 2002, 34: 3191~3198
    [22]Buchheit R G, Guan H, Mahajanam S, et al. Progress in Organic Coatings [J], 2003, 47: 174~182
    [23]Zhang F, Liu Z G, Zeng R C, et al. Surface Coating Technology[J], 2014, 258: 1152~1162
    [24]Wu F X, Liang J, Peng Z J, et al. Applied Surface Science[J], 2014, 313: 834~842
    [25]Dou B, Wang Y, Zhang T, et al. Journal of The Electrochem. Society[J], 2016, 163: 917~926
    [26]Zhang G, Wu L, Tang A, et al. Journal of The Electrochem. Society[J], 2018, 165: 317~325
    [27]Xie Y Y, Yuan X Z, Wu Z B. Journal of Colloid and Interface Science[J], 2019, 536: 440~452
    [28]Kushwaha S., Sreedhar B., Sudhakar P P. Bioresource Technololy [J], 2012, 116: 15~24
    [29]Liu Y, Yu T, Cai R, et al. Rsc Advance [J], 2015, 5: 29552~29562
    [30]American Society for Testing and Materials ASTM D 3359B-02
    Cited by
    Comments
    Comments
    分享到微博
    Submit
Get Citation

[Liang Siyan, Ren weiwei, Lin Wenxin, Zou Linchi, Cui Xiping, Chen Junfeng. In situ preparation MgCr-LDH layer on MAO coating of Mg alloy and study its anti-corrosion protection mechanism[J]. Rare Metal Materials and Engineering,2020,49(8):2830~2838.]
DOI:10.12442/j. issn.1002-185X.20190621

Copy
Article Metrics
  • Abstract:782
  • PDF: 1235
  • HTML: 150
  • Cited by: 0
History
  • Received:July 27,2019
  • Revised:September 23,2019
  • Adopted:October 11,2019
  • Online: September 27,2020