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Home > Archive>Volume 51, Issue 11, 2022 >4166-4172. DOI:10.12442/j.issn.1002-185X.20210866
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Effect of binder composition on corrosion behavior of Ti(C,N)-based cermets
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State Key Laboratory of Materials Formation and Die Mould Technology,School of Materials Science and Engineering,Huazhong University of Science and Technology

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    Abstract:

    Corrosion behavior of two Ti(C,N)-based cermets with 38 wt.% Ni or Ni–20Cr binder was investigated in 0.2 M H2SO4 and 0.2 M NaOH solutions at room temperature. In 0.2 M H2SO4 solution, there were significant differences in corrosion behavior and resistance between both cermets. For cermet with Ni–20Cr binder, binder phase was very slowly dissolved during immersion, mainly due to that the spontaneous formations of NiO, Ni(OH)x(SO4)y, Cr2O3 and Cr(OH)3, and no passivation occurred and current density steeply increased beyond the pseudo-passive region during potentiodynamic polarization, differing from cermet with Ni binder. By contrast, in 0.2 M NaOH solution, there were no significant differences in corrosion behavior and resistance between both cermets. For both cermets, ceramic grains were very slowly dissolved during immersion, accompanied by the formations of NiOOH and Cr6+ compound, and no passivation but pseudo-passivation occurred during potentiodynamic polarization.

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[Yang Qingqing, Xiong Weihao, Huang Bin, Chen Shan. Effect of binder composition on corrosion behavior of Ti(C, N)-based cermets[J]. Rare Metal Materials and Engineering,2022,51(11):4166~4172.]
DOI：10.12442/j. issn.1002-185X.20210866

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History
  • Received:October 04,2021
  • Revised:March 12,2022
  • Adopted:March 25,2022
  • Online: December 02,2022
  • Published: November 30,2022

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