+Advanced Search
  • Article
  • | |
  • Metrics
  • |
  • Reference [22]
  • |
  • Related
  • | | |
  • Comments
    Abstract:

    TA19 titanium alloy was ignited by friction oxygen concentration method, and two ignition damage samples after critical ignition and sustained combustion under oxygen enriched conditions were obtained. The phase composition, microstructure morphology and its formation mechanism of TA19 titanium alloy combustion products were studied by scanning electron microscopy (SEM), energy spectrum analysis (EDS) and X-ray diffraction (XRD). Results show that: The critical ignition products of TA19 titanium alloy mainly include TiO, Ti3O, rutile type and anatase type TiO2, and the initial combustion temperature is about 500℃. While the sustained combustion products of TA19 titanium alloy mainly include TiO, rutile type TiO2. Combined with the tetragonal structure ZrO2 formed in the fusion zone, the continuous combustion temperature is judged to be above 1170℃.Four distinct zones form from the combustion surface to the alloy matrix, and they are in the sequence of combustion zone, fusion zone, heat-affected zone and transition zone. During critical ignition, Zr solid solution rich in O, α-Ti solid solution rich in O and β phase rich in Al/Sn/Mo are formed in the fusione zone; A large amount of α-Ti solid solution rich in O and a small amount of β phase rich in Al/Sn/Mo are formed in the heat-affected zone. During sustained combustion, Al solid solution rich in O, Zr solid solution rich in O, α-Ti solid solution rich in O and β phase rich in Al/Sn/Mo are formed in the fusion zone; A large amount of α-Ti solid solution rich in O and a small amount of β phase rich in O and Zr are formed in the heat affected zone, finally they form a dense layered structure that prevents the inward diffusion of O and outward diffusion of Ti. In the combustion process of TA19 titanium alloy, the element Zr first diffuses into the interface of the fusion zone, followed by Al. This is different from that Al first diffuses to the interface of the fusion zone during the combustion of TA15 titanium alloy. The reason may be that the Zr content in TA19 titanium alloy is twice that in TA15 titanium alloy, and the activity of Zr is higher. The main combustion mechanism of near α type titanium alloy is the formation of O- rich solid solution. From the perspective of microstructure, higher equiaxed phase content is conducive to the dissolution of oxygen; From the point of view of alloy composition, proper control of the content of Ti, Al and Zr is beneficial to obtain dense O-rich solid solution.

    Reference
    [1] Li Jinyuan(李进元),Liao Qiang(廖强),Li Wei(李维). Hot Working Technology[J],2015,44(17):146~148
    [2] Zhang Jianguo(张建国),Sun Yanping(孙艳萍),Feng Shousheng(冯守胜). New Technology & New Products of China[J],2015,10(19):93
    [3] Zhu Xuefeng(朱雪峰),Yu Richeng(余日成),Huang Yanhua(黄艳华) et al. Heat Treatment of Metals[J],2015,40(2):103~106
    [4] Zhang Jing(张晶),Zhang Tiancang(张田仓),Li Ju(李菊) et al. Hot Working Technology[J],2017,46(17):59~63
    [5] Xu Shasha(许莎莎). Dissertation of Master[D],Nanjing:Nanjing University of Aeronautics and Astronautics,2019
    [6] Song Youpeng(宋有朋),Liang wenping(梁文萍),Miu Qiang(谬强) et al. Heat Treatment[J],2017,32(2):10~14
    [7] Mi Guangbao(弭光宝),Huang Xu(黄旭),Cao Jingxia(曹京霞),et al. Journal of Aeronautical Materials[J],2016,36(3):20~26
    [8] Wang Weiwei(王巍巍),Chen Yujie(陈玉洁),Gao Haihong(高海红). Gas Turbine Experiment and Research[J],2013,26(5):55~58
    [9] A.V.Grosse,J.B.Conway. Industrial and Engineering Chemistry[J], 1958,50(4):663~672
    [10] Zhao Yongqing(赵永庆),Zhou Lian(周廉),Deng Ju(邓炬). Rare Metal Materials and Engineering[J],1999,28(3):132~135
    [11] Mi Guangbao(弭光宝), Huang Xiusong(黄秀松), Li Peijie(李培杰) et al. Transactions of Nonferrous Metals Society of China[J], 2012, 22(10): 2409-2415.
    [12] Mi Guangbao(弭光宝),Huang Xu(黄旭),Cao Jingxia(曹京霞) et al. Acta Metallurgica Sinica[J],2014,50(5):575~586
    [13] Mi Guangbao(弭光宝),Huang Xu(黄旭),Cao Jingxia(曹京霞) et al. Acta Physica Sinica[J],2016, 65(5): 56103.
    [14] Chen Yongnan(陈永楠),Yang Wenqing(杨雯清),Yang Zehui(杨泽慧) et al. Rare Metal Materials and Engineering[J],2019,48(11): 3608~3614
    [15] Yang Feng(杨峰),Ran Longcheng(冉隆城),Liu Yjing(刘静) et al. Heat Treatment of Metals[J],2018,43(7):28~32
    [16] Tan Yexia(覃业霞),Lv Weijie(吕维洁),Xu Dong(徐栋) et al. Rare Metal Materials and Engineering[J],2006,35(10):1647~ 1650
    [17] Sui Nan(隋楠),Mi Guangbao(弭光宝),Yan Mengqi(颜孟奇) et al. Rare Metals[J],2018,37(11):952~960
    [18] Shen Feng(谌峰),Li Yan(李艳). Hot Working Technology[J], 2008,37(7):86~98
    [19] Zhang Jun(张钧),Ma Hongfeng(马鸿峰). Journal of Shenyang University(Natural Science)[J],2006,18(04):1~4
    [20] Zhang Kezhao(张可召). Dissertation of Master[D],Harbin: Harbin Institute of Technology,2012
    [21] Gaddam R,Sefer B,Pederson R et al. Materials Characerization[J], 2015, (99):166~174
    [22] Liu Guili(刘贵立),Li Yong(李勇). Acta Physica Sinica[J],2012,61(17):177101
    Related
    Cited by
    Comments
    Comments
    分享到微博
    Submit
Get Citation

[Sui Nan, Mi Guangbao, Cao Jingxia, Huang Xu, Cao Chunxiao. Characteristics and Formation Mechanism of Near α Type High Temperature Titanium Alloy Combustion Microstructure Under Oxygen Enriched Conditions[J]. Rare Metal Materials and Engineering,2022,51(9):3263~3275.]
DOI:10.12442/j. issn.1002-185X.20220041

Copy
Article Metrics
  • Abstract:782
  • PDF: 1113
  • HTML: 119
  • Cited by: 0
History
  • Received:January 15,2022
  • Revised:February 06,2022
  • Adopted:March 07,2022
  • Online: October 08,2022
  • Published: September 27,2022