The influence of lithium-ion occupation on its structure and properties of Li4Ti5O12

doi:10.12442/j.issn.1002-185X.20220707

Home > Archive>Volume 52, Issue 9, 2023 >3295-3301. DOI:10.12442/j.issn.1002-185X.20220707

The influence of lithium-ion occupation on its structure and properties of Li4Ti5O12
DOI:
                        10.12442/j.issn.1002-185X.20220707
                    
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                        Wang YingWang Ying
School of Mechanical and Automotive Engineering,Shanghai University of Engineering Science
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He BaojiaHe Baojia
School of Mechanical and Automotive Engineering,Shanghai University of Engineering Science
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Xing YanfengXing Yanfeng
School of Mechanical and Automotive Engineering,Shanghai University of Engineering Science
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Huang BoHuang Bo
School of Mechanical and Automotive Engineering,Shanghai University of Engineering Science
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Zhang HengyunZhang Hengyun
School of Mechanical and Automotive Engineering,Shanghai University of Engineering Science
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Affiliation:School of Mechanical and Automotive Engineering,Shanghai University of Engineering Science
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Abstract:

Li₄Ti₅O₁₂ has excellent structural stability and high safety under fast charging and discharging conditions. Therefore, it was favored by the field of new energy vehicles and energy storage. Ample researchers have focused on Li ions intercalation process of lithium titanate, Studies have shown that the discharge process is the external and all the lithium ions located at 8a position are transferred to 16c position, and the capacity of lithium titanate is limited by the number of lattice sites and reversible lithium ions involved in it. However, the lithium titanate unit cell structure suggests that the lattice sites that accommoddate lithium ions do not stop there. Li ions may replace Ti atoms occupy the octahedral 16d site, locate in tetrahedral 48f sites, reoccupy with 8a sites of the tetrahedron vacated after the phase change. This article mainly reviews, treated by chemical or electrochemical methods in the preparation process and finished product, compared with the normal LTO discharge start and end, the Li ions occupation changes and influence. Meanwhile, this paper discusses and analyzes the underlying mechanism between this change and effect.

Key words:Lithium titanate; Lattice occupation; Lithium-ion battery

Reference

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[Wang Ying, He Baojia, Xing Yanfeng, Huang Bo, Zhang Hengyun. The influence of lithium-ion occupation on its structure and properties of Li₄Ti₅O₁₂[J]. Rare Metal Materials and Engineering,2023,52(9):3295~3301.]
DOI：10.12442/j. issn.1002-185X.20220707

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Received:September 05,2022
Revised:November 11,2022
Adopted:November 24,2022
Online: September 25,2023
Published: September 21,2023

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