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Influence of the Ca- or P-containing Electrolyte Compositions on Properties of Micro-arc Oxidation Coatings Fabricated on Mg Alloy
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    Abstract:

    Micro-arc oxidation was conducted on AZ31 Mg alloy under CC mode by single variable experiments to improve its corrosion resistance and bio-activity. The microstructure, Ca/P ratio and corrosion rate were studied to investigate the influence of the Ca- or P-containing compositions on the coating. Furthermore, the properties of the optimized coating were studied. The results reveal that Ca/P ratio depends on the concentration of Ca(Ac)2, (Na2PO3)6 and NaH2PO4. With the increase of Ca(Ac)2, the coating thickness decreases, but it becomes more uniform; while (Na2PO3)6 has little effects on surface morphology or coating thickness. The content of P increases with (Na2PO3)6. The more NaH2PO4, the bigger the pore size and the smaller Ca/P ratio. The optimized coating possesses a flat and compact surface covered by micropores with diameters of about 10.7 μm and there are microcracks. And the coating phases are mainly MgO, Mg and a small amount of Ca2P2O7 and SiO2, which make the coating harder and more resistant to corrosion. The coating roughness Ra is 0.4482 μm and the wetting angle is 42.65°, which are good for cells to adhere to and grow on.

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[Xu Lei, Wang Zexin, Du Cuiling, Chen Jing, Lu Sheng. Influence of the Ca- or P-containing Electrolyte Compositions on Properties of Micro-arc Oxidation Coatings Fabricated on Mg Alloy[J]. Rare Metal Materials and Engineering,2015,44(10):2576~2582.]
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History
  • Received:October 28,2014
  • Revised:
  • Adopted:
  • Online: July 13,2016
  • Published: